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University of Cambridge > Talks.cam > Isaac Newton Institute Seminar Series > Soft Skyrmions and Programmable Self-Assembly of Superlattices
Soft Skyrmions and Programmable Self-Assembly of SuperlatticesAdd to your list(s) Download to your calendar using vCal
If you have a question about this talk, please contact INI IT. This talk has been canceled/deleted Materials whose fundamental units are nanocrystals (NC)s, instead of atoms or molecules, are gradually emerging as major candidates to solve many of the technological challenges of our century. Those materials display unique structural, dynamical and thermodynamical properties, often reflecting deep underlying geometric, packing and topological constraints. In this talk, I will discuss the rational design of NC materials by programmable self-assembly. I will present the Orbifold Topological Model (OTM), which successfully describes the structure of crystal or quasicrystal arrangements of NCs (superlattices) by considering capping ligands as Skyrmion textures, which determine the bonding very much like atomic orbitals in lattices of simple atoms. I will show that the OTM describes “atomic orbitals” as consisting of vortices, which enable the generation of a spontaneous valence and reveal the universal tendency of these systems towards icosahedral order, allowing to describe them as quasi-Frank-Kasper phases. These results will be confirmed by numerical simulations. I will elaborate on the success of the OTM in describing all existing experimental structural data on single component and binary superlattices obtained by solvent evaporation and present new candidate phases. This talk is part of the Isaac Newton Institute Seminar Series series. This talk is included in these lists:This talk is not included in any other list Note that ex-directory lists are not shown. |
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