University of Cambridge > Talks.cam > Synthetic Chemistry Research Interest Group > Harnessing Radicals and Carbenes To Enable Unconventional Reactivity

Harnessing Radicals and Carbenes To Enable Unconventional Reactivity

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Radical chemistry can afford opposite or orthogonal reactivity to classic two-electron pathways. By developing radical chaperone strategies that merge open (1e-) and closed shell (2e-) processes, we have harnessed this complementary reactivity and imparted new types of chemo-, regio-, and stereo- selectivity for remote, double, or reversed C-H and C-O functionalizations of alcohols, amines, and carbonyls. These radical chaperone tools are continually being developed to streamline the synthesis of complex, medicinally relevant molecules and heterocycles.

This talk is part of the Synthetic Chemistry Research Interest Group series.

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