Complex architecures of conjugated polymers via Suzuki and Kumada chain-growth polycondensations
- π€ Speaker: Dr Anton Kiriy (Leibniz-Institut fΓΌr Polymerforschung Dresden e.V.)
- π Date & Time: Thursday 11 March 2010, 16:00 - 17:00
- π Venue: Wolfson Lecture Theatre, Department of Chemistry
Abstract
Unlike the situation with nonconductive polymers where variety of polymer architectures (block copolymers, polymer brushes, start, etc.) are readily available, a synthetic toolbox is much less developed in the case of conjugated (conductive) polymers. Recently, we developed surface/site-initiated Ni- and Pd-mediated catalyst transfer chain-growth polycondensations. To date, methods to grow conductive polymer brushes, hairy particles and stars of regioregular poly(3-alkylthiophenes), polyfluorenes and other conjugated polymers were developed. In this talk I would like to review our recent results in this field, including application of the obtained structures in photovoltaics and discuss an intriguing ring-walking polycondensation mechanism, responsible for the selective formation of such structures.
Series This talk is part of the Melville Laboratory Seminars series.
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Dr Anton Kiriy (Leibniz-Institut fΓΌr Polymerforschung Dresden e.V.)
Thursday 11 March 2010, 16:00-17:00